Where can I find the chart/matrix describing what pilot qualifications are required for certain flights to adhere to FAA exemption?

The CAP FAA Exemption chart is located on the “CAP Pilots” web page in the “FAA & ICAO Information” section and the various CAP pilot qualifications are explained in CAPR 70-1.  

As the Civil Air Patrol conducts a wide variety of aviation mission types while using several different Pilot rating/endorsements, it would be best to utilize the local expertise in your chain of command to help with matching required Pilot qualifications to the CAP aviation mission types where FAA exemptions apply; your Unit, Wing, and Region Stan/Eval Officers are a wealth of knowledge and are ready to assist.